Burning Rate Depends on Oxygen Concentration
Kinetics of the Decomposition of Hydrogen Peroxide by Permanganate
Kinetics of Oxidation of Iodine Ion by Peroxide
Reaction Rate Depends on Particle Size
Autocatalysis of Oxalate Ion With Permanganate
Catalytic Decomposition of Hydrogen Peroxide
Explosions of Lycopodium and Other Powders
Old Nassau: The Landolt Reaction With Mercury Indicator
Catalytic Oxidation of Ammonia
Ignition of Hydrogen on a Platinum Catalyst
Slow Decolorization of Permanganate by Ethanol
Visible Reactive Intermediate
Description: A mixture of tartrate ion and hydrogen peroxide does not react, even at 70°C. Adding cobalt as a catalyst causes the reaction to proceed; the color of the mixture changes from pink to green, accompanied by considerable foam.
Source: Fun with Chemistry; A Guidebook of K-12 Activities Institute for Chemical Education Ed by M. and J. Sarquis
Year: 1993 Vol: 2 Page: 253
Keywords: Kinetics, Cobalt, Tartrate, Hydrogen peroxide, Catalyst
Ratings:
Hazard: Medium
- Acute toxicity hazard
- Skin corrosion hazard
- Serious eye damage
- Inhalation hazard
- Electric shock hazard
- Burn hazard
- Scald hazard
- Aquatic toxicity
- Carcinogenicity hazard
- Reproductive toxicity hazard
- Dermal exposure hazard
- Specific organ toxicity – respiratory system
Effectiveness: Excellent
- Good connection from demo to course material
- Obvious contrast between behavior of systems
- Spectacular or counter intuitive effects are seen
- Time to results is low
- High reliability
Difficulty: Medium
- Some concerted manipulations
- Reactions of demos at non-standard conditions
- Reactions contain potential for the creation of hazardous conditions
Safety Precautions:
- Eye protection required
- Gloves required
- Thermal gloves required
- Use of UL approved three-prong plug and outlet
- Absorbent materials on hand
- Containment required
- Perform in a well-ventilated area
- Perform on a chemically resistant surface
- Avoid exposure to gases, mists or dusts
- Prevent release of reagents to the environment
Class: Catalysis, Kinetics
Division: General
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