Organic Chemistry- Oxidation of Luminol

Bromination of Saturated and Unsaturated Hydrocarbons

Blue Bottle

Dehydration of Sugar by Sulfuric Acid

Disappearing Coffee Cup

Formation of a Silver Mirror

Models 360

Nylon 6 – 10

Organic Synthesis With Familiar Materials

Oxidation of Primary, Secondary, Tertiary Alcohols

Oxidation of Luminol

Polyurethane  Foam

Slime

Underwater Fireworks: Chlorination of Acetylene

Carbide Lamp

Differences in Miscibility of Organic Alcohols With Increasing Chain Length

Combustion of Cellulose Nitrate (Guncotton)

Different Smells  of Carvone Isomers

Distinguishing Between HD and LD Polyethylene

Enviro-Bond: Cleaning Oil Spills

Esterification Using a Dean-Stark Trap

Ethanol Cannon

Happy/Sad Balls

IR Demonstration I – Atomic Coupling

IR Demonstration II – Molecular Vibrations

IR Demonstrations III – Molecular Vibrations

Making a Rubber Ball from Latex

Plastic Samples

Reaction Intermediates in Organic Chemistry

Reducing Sugars and Fehling’s Solution

Rod Climbing by a Polymer Solution

Rotating Rainbows

Silly Putty

Soap Emulsifies Hydrocarbons

Superabundant Polyacrylate Gel

Tubeless Siphon

Alkimers

Aniline Hydrochloride-Formaldehyde Polymer

Phenol-Formaldehyde Polymer

Saponification

Relative Reactivity of Reducing Agents

Electrophilic Aromatic Substitution Reaction/EAS Reaction

Reactivity of Alkanes vs Aromatic Compounds

Inductive Effect

Optical Activity of Racemic Mixtures With Limonene

Relationship of Absorbed Light to Observed Color

Density and Miscibility of Liquids

Extraction of Copper Ions from Solution with Orform®

Gel Formation with Sodium Alginate and Calcium Chloride

Ozonolysis

Hydrolysis of T-Butyl Chloride: A Lecture and Lab Experiment

Oxidation of Luminol

Description: Two solutions are poured together in the dark and emit a bright blue glow.

Source: Shakhashiri,B.Z  Chemical Demonstrations: A Handbook for Teachers of Chemistry

Year: 1983  Vol:Page: 156

Keywords: Luminol, 3-Aminophthalhydrazide, Chemiluminescence, Oxidation, Spin state, Diels-Alder Reaction

Rating:

Hazard: Some

  • Mild toxicity hazard
  • Skin corrosion hazard
  • Oxidizer
  • Inhalation hazard
  • Corrosive to metals
  • Aquatic toxicity hazard
  • Trip hazard

Effectiveness: Excellent

  • Obvious contrast between systems
  • Results are clearly observable without guidance
  • Superior reliability
  • Good connection from demo to course material
  • Time to results is very low
  • Mild effects are seen by audience

Difficulty: Some

  • Simple procedures
  • Manipulations are simple for most to perform
  • Step stool may be required
  • Prior practice recommended
  • Portions of reactions are performed in the dark

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Avoid exposure to droplets, mists, and vapors
  • Avoid obstructions during performance
  • Absorbent materials on hand
  • Expect portions of the experiment will be performed in low light
  • Prevent release of reagents to the environment

Class: Organic Chemistry

Division: General, Organic Chemistry