Organic Chemistry- Extraction of Copper Ions From Solution With Orform®

Bromination of Saturated and Unsaturated Hydrocarbons

Blue Bottle

Dehydration of Sugar by Sulfuric Acid

Disappearing Coffee Cup

Formation of a Silver Mirror

Models 360

Nylon 6 – 10

Organic Synthesis With Familiar Materials

Oxidation of Primary, Secondary, Tertiary Alcohols

Oxidation of Luminol

Polyurethane Foam

Slime

Underwater Fireworks: Chlorination of Acetylene

Carbide Lamp

Differences in Miscibility of Organic Alcohols With Increasing Chain Length

Combustion of Cellulose Nitrate (Guncotton)

Different Smells of Carvone Isomers

Distinguishing Between HD and LD Polyethylene

Enviro-bond: Cleaning Oil Spills

Esterification Using a Dean-Stark Trap

Ethanol Cannon

Happy/Sad Balls

IR Demonstration I – Atomic Coupling

IR Demonstrations II – Molecular Vibrations

IR Demonstration III – Molecular Vibrations

Making a Rubber Ball frpom Latex

Plastic Samples

Reaction Intermediates in Organic Chemistry

Reducing Sugars and Fehling’s Solution

Rod Climbing by a Polymer Solution

Rotating Rainbows

Silly Putty

Soap Emulsifies Hydrocarbons

Superabsorbent Polyacrylate Gel

Tubeless Siphon

Alkimers

Aniline Hydrochloride-Formaldehyde Polymer

Phenol-Formaldehyde Polymer

Saponification

Relative Reactivity of Reducing Agents

Inductive Effect

Optical Activity of Racemic Mixtures With Limonene

Electrophilic Aromatic Substitution Reaction/EAS Reaction

Reactivity of Alkanes vs. Aromatic Compounds

Relationship of Absorbed Light to Observed Color

Density and Miscibility of Liquids

Extraction of Copper Ions From Solution With Orform®

Gel Formation with Sodium Alginate and Calcium Chloride

Ozonolysis

Hydrolysis of T-Butyl Chloride: A Lecture and Lab Experiment

Extraction of Copper Ions from Solution with Orform®

Description: Copper sulfate(aq) is added to the organic Orform® solution and shaken. The system is acidified, and the Copper ions migrate from the Orform® to the aqueous phase. With the addition of base, the copper ions migrate from the aqueous phase to the organic phase, which can be easily noted based on the color of the aqueous phase of the mixture. This process is used industrially for the separation of Cu ions from mineral phases during mining operations. This demo is a good example of industrial chemistry, organometallic chemical systems, phase separation and transition metal behaviors in solution. This demo features chelation, an important concept in biological and industrial purification chemistry. The organic solution is a product of the Chevron corporation.

Source: Landis, Clark Prof.

Year: 2014   Vol: N/A    Page: N/A

Keywords: Copper, Extraction, Orform®, Acid, Base Chelate, Organometallics

Rating:

Hazard: Medium

  • Flammable
  • Skin irritation
  • Skin corrosion hazard
  • Aspiration hazard
  • Corrosive to metals
  • Serious eye damage
  • Acute aquatic toxicity

Effectiveness: Good

  • Deep connection from demo to course material
  • Results are observable with guidance
  • Mild effects are seen by audience
  • Time  to results is medium

Difficulty: Medium

  • Use of scientific glassware
  • Volume-dependent addition for proper results
  • Use of toxic reagents
  • Some intermediate steps to results

Safety Precautions:

  • Eye protection required
  • Gloves required
  • No open flames
  • Avoid contact with liquids or vapors
  • Absorbent material on hand
  • Sodium bicarbonate on hand

Class: Organometallics, Chelation

Division: Inorganic Chemistry, Organic Chemistry