Organic Chemistry- Optical Activity of Racemic Mixtures With Limonene

Bromination of Saturated and Unsaturated Hydrocarbons

Blue Bottle

Dehydration of Sugar by Sulfuric Acid

Disappearing Coffee Cup

Formation of a Silver Mirror

Models 360

Nylon 6 – 10

Organic Synthesis With Familiar Materials

Oxidation of Primary, Secondary, Tertiary Alcohols

Oxidation of Luminol

Polyurethane Foam

Slime

Underwater Fireworks: Chlorination of Acetylene

Carbide Lamp

Differences in Miscibility of Organic Alcohols With Increasing Chain Length

Combustion of Cellulose Nitrate (Guncotton)

Different Smells of Carvone Isomers

Distinguishing Between HD and LD Polyethylene

Enviro-bond: Cleaning Oil Spills

Esterification Using a Dean-Stark Trap

Ethanol Cannon

Happy/Sad Balls

IR Demonstration I – Atomic Coupling

IR Demonstrations II – Molecular Vibrations

IR Demonstration III – Molecular Vibrations

Making a Rubber Ball With Latex

Plastic Samples

Reaction Intermediates in Organic Chemistry

Reducing Sugars and Fehling’s Solution

Rod Climbing by a Polymer Solution

Rotating Rainbows

Silly Putty

Soap Emulsifies Hydrocarbons

Superabsorbent Polyacrylate Gel

Tubeless Siphon

Alkimers

Aniline Hydrochloride-Formaldehyde Polymer

Phenol-Formaldehyde Polymer

Saponification

Relative Reactivity of Reducing Agents

Inductive Effect

Optical Activity of Racemic Mixtures With Limonene

Electrophilic Aromatic Substitution Reaction/EAS Reaction

Reactivity of Alkanes vs Aromatic Compounds

Relationship of Absorbed Light to Observed Color

Density and Miscibility of Liquids

Extraction of Copper Ions from Solution with Orform®

Gel formation with Sodium Alginate and Calcium Chloride

Ozonolysis

Hydrolysis of T-Butyl Chloride: A lecture and Lab Experiment

Optical Activity of Racemic Mixtures With Limonene

Description: A sample of S-(+)- limonene is placed in a large cuvette glass made for this experiment and placed between two polarizers on an overhead projector. the optical activity is noted by the prismatic effect that occurs while changing the relative position of the two polarizers filter lines.

Source: Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry, Bowman, Matt  Dr.

personal consult (2018)

Year: 1989 Vol. 3    Page386 – 398

Keywords: Limonene, Polarized light.  Optical activity,  Racemic mixture,  Isomer, Enantiomer

Rating:

Hazard: Some

  • Flammable liquids
  • Skin sensitization hazard
  • Aspiration hazard
  • Short-term (acute) aquatic hazard
  • Long-term (chronic) aquatic hazard
  • Skin irritation hazard
  • Electric shock hazard
  • Breakage hazard

Effectiveness: Good

  • Primary effects
  • Results are observable with guidance
  • Good connection from demo to course material
  • Time to results is medium
  • High reliability

Difficulty: Medium

  • Some careful manipulation required
  • Some intermediate steps to results
  • Use of toxic reagents
  • Use of electrical equipment

Safety Precautions:

  • Eye protection required
  • Gloves required
  • PPE required
  • Avoid inhalation of mists, droplets, or vapors
  • Use of UL approved three prong plug and outlet
  • ABC fire extinguisher on hand
  • Prevent release of reagents to the environment
  • Absorbent materials on hand
  • Perform in a well-ventilated area
  • Prior training recommended
  • Observation distance one meter minimum

Class: Physical Properties of Organic Compounds

Division: Organic Chemistry