Organic Chemistry- Aniline Hydrochloride-Formaldehyde Polymer

Bromination of Saturated and Unsaturated Hydrocarbons

Blue Bottle

Dehydration of Sugar by Sulfuric Acid

Disappearing Coffee Cup

Formation of a Silver Mirror

Models 360

Nylon 6 – 10 

Organic Synthesis With Familiar Materials

Oxidation of Primary, Secondary, Tertiary Alcohols

Oxidation of Luminol

Polyurethane Foam

Slime

Underwater Fireworks: Chlorination of Acetylene

Carbide Lamp

Differences in Miscibility of Organic Alcohols With Increasing Chain Length

Combustion of Cellulose Nitrate (Guncotton)

Different Smells of Carvone Isomers

Distinguishing Between HD and LD Polyethylene

Enviro-bond: Cleaning Oil Spills

Esterification Using a Dean-Stark Trap

Ethanol Cannon

Happy/Sad Balls

IR Demonstration I – Atomic Coupling

IR Demonstration II – Molecular Vibrations

IR Demonstration III – Molecular Vibrations

Making a Rubber Ball from Latex

Plastic Samples

Reaction Intermediates in Organic Chemistry

Reducing Sugars and Fehling’s Solution

Rod Climbing by a Polymer Solution

Rotating Rainbows

Silly Putty

Soap Emulsifies Hydrocarbons

Superabsorbent Polyacrylate Gel

Tubeless Siphon

Alkimers

Aniline Hydrochloride-Formaldehyde Polymer

Phenol-Formaldehyde Polymer

Saponification

Relative Reactivity of Reducing Agents

Inductive Effect

Electrophilic Aromatic Substitution Reaction/ EAS Reaction

Reactivity of Alkanes vs Aromatic Compounds

Optical Activity of Racemic Mixtures With Limonene 

Relationship of Absorbed Light to Observed Color 

Density and Miscibility of Liquids

Extraction of Copper Ions from Solution with Orform®

Gel Formation with Sodium Alginate and Calcium Chloride

Ozonolysis

Hydrolysis of T-Butyl Chloride: A Lecture and Lab Experiment

Aniline Hydrochloride-Formaldehyde Polymer

Description: Solutions of aniline hydrochloride and formaldehyde, when mixed, solidify within seconds to a red, rubbery mass accompanied by a temperature rise of about 40° C. This demonstration is performed in a hood.

Source: Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry

Year: 1983   Vol:Page: 225

Keywords: Polymers, Aniline, Formaldehyde, Plastics

Rating:

Hazard: High

  • Acute toxicity hazard – oral, dermal, inhalation
  • Flammability hazard
  • Serious eye damage
  • Carcinogenicity hazard
  • Short and long term aquatic hazard
  • Mutagenicity hazard
  • Skin corrosion hazard
  • Inhalation hazard
  • Specific organ target toxicity – eyes, blood, respiratory system

Effectiveness: Good

  • Results are clearly observable without guidance
  • Time to result is low
  • Good connection from demo to course material
  • Effects are engaging

Difficulty: High

  • Multi-step procedure
  • Reaction using toxic compounds
  • Use of flammable reagents
  • Some sequential manipulations

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Lab coat required
  • Use of downdraft hood required
  • Absorbent material on hand
  • Not to be performed in discussion room
  • ABC fire extinguisher on hand
  • Thermal gloves recommended
  • Prevent release of reagents to the environment

Class: Organic Chemistry, Polymers

Division: General Chemistry, Organic Chemistry