Gases- Rate of Diffusion: The Ammonium Chloride Ring

Rate of Diffusion: The Ammonium Chloride Ring

Description: Ammonia gas and hydrogen chloride gas are introduced at opposite ends of a long air-filled glass tube. After about 15-20 minutes, a very localized cloud of white ammonium chloride forms where the two gases meet after diffusing through the air. The location is relative to the molecular masses of two gases.

Source:  Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry

Year: 1985  Vol: 2  Page: 59

Keywords: Diffusion; Graham’s Law, Kinetic Molecular theory, Molecular speeds, Path length

Rating:

Hazard: Medium

  • Acute toxicity hazard – inhalation, ingestion, oral
  • Serious eye damage
  • Skin corrosion hazard
  • Specific exposure hazard to the eye, lungs
  • Aquatic toxicity hazard
  • Corrosive to metals
  • Spill hazard

Effectiveness: Good

  • Good connection from demo to course material
  • Some contrast between behavior of systems
  • Time to results is high, greater than 20 minutes
  • Moderate failure rate
  • Results are observable with guidance

Difficulty:  Medium

  • Some concerted or timed manipulations
  • Use of reactive substances
  • Simultaneous manipulations
  • Demos at non-standard conditions
  • Prior training required
  • Simple procedures

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Perform in a well-ventilated area
  • Chemically resistant surface required
  • Downdraft hood recommended
  • Absorbent material on hand
  • Sodium bicarbonate solution on hand
  • Prevent release of reagents to the environment

Class: Gases, Acid-Base Reaction, Kinetics

Division: General, Physical Chemistry