Thermodynamics- Volume Increase Upon Neutralization

Volume Increase upon Neutralization

Description: When equal volumes of strong aqueous acid and base are mixed,  the resulting volume is more than the simple sum of the volumes, due to the formation of water.

Source: Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry

Year: 1989  Vol:Page: 276

Keywords: Acid Base Chemistry, Water, Hydrochloric Acid, Sodium Hydroxide

Ratings:

Hazard: Medium

  • Serious eye damage hazard
  • Corrosive to metals
  • Skin corrosion hazard
  • Inhalation hazard
  • Acute toxicity hazard

Effectiveness: Good

  • Good connection from demo to course material
  • Some contrast between system behavior
  • Results can be observed with guidance
  • Low failure rate
  • Time to result is medium

Difficulty: Medium

  • Careful manipulations required
  • Procedures with some intermediate steps to results
  • Demos in which a display is used
  • Volume dependent addition for proper results

Safety Precautions:

  • Gloves required
  • Eye protection required
  • Chemically resistant surface required
  • Sodium bicarbonate on hand
  • Absorbent materials on  hand
  • Uses UL approved three-prong plug and outlet
  • Perform in a well-ventilated area
  • Prevent release of reagents to the environment

Class: Intermolecular Forces, Solubility, Properties of Solutions, Acid-base Reaction, Thermodynamics

Division: General, Physical Chemistry

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