Reduction/Oxidation Reaction- Blue Bottle

Blue Bottle

Description: A bottle half-full of a colorless liquid is shaken and turns blue. On standing undisturbed, the blue color fades. The cycle may be repeated several times. Other colors can be produced by substituting other indicators for the methylene blue commonly used.

This demonstration is also available on JCE “Chemistry Comes Alive!” Vol 3 CD-Rom

Source: Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry.

Year: 1985 Volume:  2  Page: 142

Keywords: Blue Bottle, Oxygen, Methylene Blue, Oxidation

Rating: 

Hazards: Some

  • Skin corrosion hazard
  • Spill hazard
  • Acute toxicity hazard
  • Short term aquatic toxicity hazard
  • Corrosive to metals
  • Serious eye damage

Effectiveness: Good

  • Some connection from demo to course material
  • Good contrast of system behavior
  • Time to results is low
  • Good reliability
  • Repeatable phenomenon
  • Mild effects are seen by audience
  • Secondary effects are observed

Difficulty: Low

  • Simple procedures
  • Simple manipulations for most to perform

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Absorbent materials on hand
  • Sodium bicarbonate on hand
  • Prevent release of reagents to the environment

Class: Acid Base Chemistry, Redox Reactions

Division: General, Organic Chemistry

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