Main Group Elements- Plastic Sulfur

Plastic Sulfur

Description: When flowers of sulfur or roll-form sulfur is heated to melting point and then poured into water, the resulting rubbery mass remains flexible until it cools. In approximately 36 hours, the sulfur returns to a crystalline form.

This demonstration is also available on on video and JCE “Chemistry Comes Alive!”  Vol.2 CD-Rom

Source: Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry

Year: 1985   Vol: 2   Page: 243

Keywords: Polymers, Sulfur, Allotrope, Melting point

Rating:

Hazard: High

  • Oxidizer
  • Burn hazard
  • Inhalation hazard
  • Acute toxicity hazard
  • Gas-producing reaction
  • Skin corrosion hazard
  • Serious eye damage
  • Flammability hazard

Effectiveness: Good

  • Results are clearly observable without guidance
  • Good connection from demo to course material
  • Strong effects are seen by audience
  • Moderate failure rate
  • Time to results is medium
  • Primary effects are observed

Difficulty: High

  • Reactions containing chemicals that form toxic compounds
  • Demos at non-standard conditions
  • Procedures with some intermediate steps to results
  • Requires attention to detail
  • Requires temperature control
  • Careful manipulations required
  • Prior practice recommended

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Perform in fume hood or downdraft hood
  • ABC fire extinguisher on hand
  • Perform on chemically resistant surface
  • Absorbent materials on hand
  • Avoid exposure to gases, mists, or vapors

 

Class: Main Group Elements, Groups VIB and VIIB (16 and 17)

Division: General, Inorganic Chemistry

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