Main Group Elements- Oxidation of Carbon by Fuming Nitric Acid

Oxidation of Carbon with Fuming of Nitric Acid

    

 

Demonstrations: Fuming Nitric Acid is added to a 5L RB flask. A lump of charcoal is heated to red hot with a Meker burner, and the charcoal is added to the flask. 

C(s) + 4HNO3 → CO2(g) + 4NO2(g) + 2H2O(l) 

Source: UW Card Catalog

Year:  N/A    Vol:  N/A   Page: N/A

Keywords: Oxidation, Carbon, Activation energy, Fuming Nitric Acid, 

Rating:

Hazard: Medium

  • Oxidizing liquids
  • Corrosive to metals
  • Acute toxicity- Inhalation, Dermal
  • Skin corrosion hazard
  • Serious eye damage
  • Flammability hazard
  • Asphyxiation hazard

Effectiveness: Average

  • Effects are clearly observable without guidance
  • Medium effects are seen
  • Some connection from demo to course material
  • Contrast between systems behavior is clear
  • Moderate failure rate
  • Time to results is medium

Difficulty: High

  • Coordinated and timed manipulations are required
  • Multi-step procedures with varying results
  • Reactions with toxic reagents and products
  • Demos at non-standard conditions

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Hot gloves required
  • Lab coat recommended
  • Perform with working fume hood, outdoors, or with a working downdraft hood
  • Open flames in use
  • ABC fire extinguisher on hand
  • Perform on a heat and chemically resistant surface
  • Perform in a well-ventilated hood
  • Avoid exposure to toxic reagents

 

 

 

Class: Redox Reactions, Main Group Elements

Division: General, Inorganic Chemistry

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