Transition Metals- Chromate-Dichromate Equilibrium

Chromate – Dichromate Equilibrium

The first photo shows a stoppered bottle with yellow liquid, a beaker with yellow liquid, a beaker with orange liquid, and a stoppered, labeled bottle with orange liquid. In the second photo, two hands each tilt a labeled bottle with clear liquids toward a beaker. The left beaker contains an orange liquid, and the right beaker contains a yellow liquid. A bottle with yellow liquid is seen behind the beaker containing  orange liquid. A bottle of orange liquid is seen behind the bottle containing yellow liquid.

Description: Yellow chromate ion is turned orange by addition of acid. The orange dichromate is returned to yellow by the addition of base. The change may be repeated several times. This illustrates LaChatelier’s Principle.

Source: UW Card Catalog

Year: N/A   Vol: N/A  Page: N/A

Keywords: Chromate ion, Acid, Base, Equilibrium, LaChatelier’s Principle.

Rating:

Hazard: High

• Skin corrosion hazard
• Acute toxicity hazard – inhalation, oral, dermal
• Serious eye damage
• Carcinogenicity hazard
• Reproductive toxicity
• Germ cell mutagenicity hazard
• Oxidizing solids
• Corrosive to metals
• Aquatic toxicity hazard

Effectiveness: Good

• Results are clearly observable without guidance
• Good connection from demo to course material
• High reliability
• Time to results is low

Difficulty: Medium

• Sequential manipulations of reagents
• Procedures with some intermediate steps with results
• Demos in which toxic reagents are in use

Safety Precautions:

• Eye protection required
• Gloves required
• Perform in a well-ventilated area
• Absorbent material on hand
• Sodium bicarbonate on hand
• Avoid exposure to dusts, mists, or droplets
• Prevent release of reagents to the environment

Class: Equilibrium, Acids and Bases, Transition Metals

Division: General, Inorganic Chemistry

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