Groups IVB and VB (14 and 15)- Leeching Lead into Acidic Solution

Leeching Lead Into Acidic Solution

Description: Two 2.0-gram samples of lead metal Pb (s) are placed in 250 mL beakers with 0.1M KI (aq). ~1mL of 9M H2SO4(aq) is added to one sample. The other serves as a reference. The acidified sample leeches lead into solution which reacts with KI (aq) to form PbI2 (s), a bright yellow precipitate. The precipitation of  PbI2(s) from 0.1M Pb(NO3)2(aq) and 0.1M KI (aq) can be performed as a precursor to the experiment. 

Source: Moore, John Prof.,  Maynard James H.

Year: 2019  Vol:  N/A  Page: N/A

Keywords: pH, Lead, Precipitate, Equilibrium

Rating:

Hazard: Some

  • Acute toxicity hazard
  • Aquatic toxicity hazard
  • Central nervous system toxicity hazard – dermal, oral
  • Skin corrosion hazard
  • Aspiration hazard

Effectiveness: Average

  • Good connection from demo to course material
  • Results are observable with guidance
  • Mild effects are seen by audience
  • Time to results is medium, approximately 20 minutes
  • High reliability

Difficulty: Medium

  • Use of toxic reagents
  • Use of strong acids
  • Some intermediate steps to results

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Perform in a well-ventilated area
  • Avoid exposure to droplets  or vapor
  • Absorbent materials on hand
  • Sodium bicarbonate on hand

Class: Acids and Bases, Transition Metal Chemistry, Solubility

Division: General, Inorganic Chemistry

Home| General Chemistry Demonstrations| Inorganic Chemistry Demonstrations