Electrochemistry- Zinc Dendrites

 Zinc Dendrites 

Description: Aqueous zinc sulfate is added to a Petri dish to just cover the bottom surface of the dish. Graphite and galvanized iron wire electrodes are connected to a 9 VDC battery. After a few minutes, dendritic crystals of Zinc form at the graphite cathode in solution. The crystals propagate toward the galvanized wire anode and will form a “bridge” between the electrodes given enough time. 

Zn2+(aq) + 2e → Zn(s)    

ZnSO4(aq) + 2e → Zn(s) + SO42−(aq)  

SO42(aq)-4e→ SO2(aq) + O2(g) 

Source: Maynard, J.H.

Year: 2023   Vol: N/A   Page: N/A

Rating:

Keywords: Zinc, Dendrites, Electrodes, Electrochemistry, Redox 

Hazard: Some

  • Acute toxicity – oral
  • Serious eye damage
  • Short-term (acute) aquatic toxicity
  • Long-term (chronic) aquatic toxicity

Effectiveness: Good

  • Time to results is low
  • Good connection from demo to course material
  • Results are observable with guidance
  • Clear contrast between systems behavior
  • Good reliability

Difficulty: Medium

  • Use of scientific equipment
  • Some intermediate steps to results
  • Demo at non-standard conditions
  • Some fine manipulations

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Use UL approved three-prong plug and outlet
  • Prevent release of reagents to the environment
  • Avoid exposure to dusts, mists, or droplets

 

Class: Electrochemistry

Division: General

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