Electrochemistry and Redox Reactions- Potentiometry With the Belousov-Zhabotinsky Reaction

Potentiometry with the Belousov-Zhabotinsky Reaction

Description: The potentiometry of this oscillating reaction is determined using a Pt wire and Ag/AgCl electrode. The periods are about 1 min. in length, and the potential varies by about 200 mV. This changes in potential are monitored on a computer. The reaction lasts about 40 minutes.

Source: Harris, Daniel C. Quanitative Chemical Analysis 2nd Edition

Year: 1999   Vol: N/A   Page: 382

Keywords: Potentiometry, BZ reaction, Oscillator, Voltage, Electrode, Kinetics

Rating:

Hazard: Some

  • Acute toxicity hazard – oral
  • Electric shock hazard
  • Skin corrosion hazard
  •  Inhalation hazard
  • Oxidizing solids
  • Specific target organ toxicity – single exposure – respiratory system
  • Corrosive to metals
  • Serious eye damage

Effectiveness: Average

  • Somewhat connected conceptually to course material
  • Mild effects are seen by audience
  • Secondary effects are seen by audience
  • Moderate failure rate

Difficulty: High

  • Use of chemically sensitive systems
  • Multi-step procedures with varying results
  • Experiments in which data recording and display are necessary
  • Use of scientific equipment
  • Simple manipulations

Safety precautions:

  • Eye protection required
  • Gloves required
  • Use of UL approved three-prong plug and outlet
  • Absorbent materials on hand
  • Sodium bicarbonate on hand
  • Sodium thiosulfate on hand
  • Perform in a well-ventilated area
  • Avoid exposure to droplets, mists, or vapors

Class: Electrochemistry and Redox Reaction, Kinetics

Division: Analytical Chemistry, Physical Chemistry