Dissociation and Solubility- Effect of Ionic Strength on Ion Dissociation

Effect of Ionic Strength on Ion Dissociation

Description: The effect of ionic strength on dissociation is tested using an iron (III) thiocyanate complex. Mixing a solution of iron (III) and KSCN produces a pale red solution. Adding potassium nitrate to the solution causes the color to fade.

Source: Harris, Daniel C. Quanitative Chemical Analysis 2nd ed.

Year: 1999    Vol: N/A  Page: 177

Keywords: Iron (III) Thiocyanate complex,  Potassium Nitrate, Ionic strength, Dissociation

Rating:

Hazard: Medium

  • Acute toxicity hazard- oral, inhalation, dermal
  • Corrosive to metals
  • Serious eye damage
  • Oxidizing liquids
  • Aquatic toxicity hazard
  • Skin corrosion hazard

Effectiveness: Good

  • Good connection from demo to course material
  • Results are clearly observable without guidance
  • Clear contrast between systems behavior
  • Low failure rate
  • Time to results is low

Difficulty: Medium

  • Some concerted or timed manipulations
  • Use of toxic substances
  • Some physical manipulations

Safety Precautions:

  • Eye protection required
  • Gloves required
  • Absorbent materials on hand
  • Avoid exposure to mists, dusts, or vapors
  • Prevent release of reagents to the environment
  • Sodium bicarbonate on hand

 

Class: Dissociation, Solubility, Equilibrium

Division: Analytical Chemistry, General Chemistry

Home| Analytical Chemistry Demos| General Chemistry Demos